γ-INDUCED ADDITION REACTION OF METHANOL TO METHYL OLEATE
نویسندگان
چکیده
منابع مشابه
Conversion of Methyl Oleate to Branched-Chain Derivatives
Studies were conducted in the synthetic conversion of oleic acid to mid-chain branched fatty acids. Methyl oleate was brominated in the allylic positions. Reaction of the allylic bromides with lithium dimethylcuprate gave primarily the desired branched-chain derivatives (93% of product mixture). The product had a significantly lower crystallization temperature in comparison with methyl oleate. ...
متن کامل1H-NMR Spectroscopy Study of Oleic Acid and Methyl Oleate Ozonation in different reaction conditions
Reactions of ozone with oleic acid or methyl oleate were carried out in presence of hexane, carbon tetrachloride, ethanol or water. All the reaction mixtures were studied by H Nuclear Magnetic Resonance Spectroscopy (H-NMR). Differences in the composition of the reaction mixture of the samples by 1H-NMR analysis were found. During the ozonation of oleic acid, the acyl-oxy-alquil-hydroperoxides ...
متن کاملMechanistic features of isomerizing alkoxycarbonylation of methyl oleate.
The weakly coordinated triflate complex [(P^P)Pd(OTf)](+)(OTf)(-) (1) (P^P = 1,3-bis(di-tert-butylphosphino)propane) is a suitable reactive precursor for mechanistic studies of the isomerizing alkoxcarbonylation of methyl oleate. Addition of CH(3)OH or CD(3)OD to 1 forms the hydride species [(P^P)PdH(CH(3)OH)](+)(OTf)(-) (2-CH(3)OH) or the deuteride [(P^P)PdD(CD(3)OD)](+)(OTf)(-) (2(D)-CD(3)OD)...
متن کاملGas-Phase Selective Conjugate Addition of Methanol to Acetone for Methyl Vinyl Ketone Over SnO2 Nanoparticle Catalysts
s of the 11o Congresso Brasileiro de Catálise and 1o Congresso de Catálise no Mercosul, Bento Gonçalves, Brazil,
متن کاملMiniemulsion polymerization of acrylated methyl oleate for pressure sensitive adhesives
The focus of this work was to improve the aqueous emulsion polymerization of a highly water-insoluble monomer derived from plant oil, acrylated methyl oleate. Conventional emulsion polymerization requires excessive amounts of surfactant and long reaction time. Miniemulsion polymerization improved the polymerization significantly. Only a fraction of the surfactant and reaction time that was nece...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1974
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1974.211